In a cocktail shaker full of ice, combine the whiskey, moonshine, vodka, and simple syrup. Shake for 10 seconds.
Dip a paper towel in the jalapeño simple syrup and rub along the rims of 2 rocks glasses. Shake out the Kentucky Bourbon Smoked Sea Salt in a circle on a shallow dish and dip the rims in the salt, coating them evenly.
Add a large ice cube and 1 peach wedge from the moonshine to each glass. Strain the drinks into the 2 glasses and enjoy.